ZipTip Protocol for LC-MS/MS

ZipTip Protocol for LC-MS/MS

Solutions Required

0.5% TFA in HPLC water

  • 5 μL of TFA in 995 μL of water

50:50 acetonitrile:water

100% Acetonitrile (ACN)

Elution Buffer (67% ACN; 32.8% Water; 0.2% TFA)

  • 670 μL of 100% acetonitrile, 328 μL of water, and 2 μL of TFA

Solvent A: 0.1% formic acid in water

This protocol is used to remove salts from the sample. The ZipTip can trap up to 2 μg of peptides/proteins.

Procedure

  1. Dry down samples in the SpeedVac.
  2. Resuspend the samples in 20  μL of solvent A.
  3. Aliquot 20  μL of elution buffer into desired number of tubes.
  4. Using the ZipTip, wash 2X with acetonitrile solution (ACN).
  5. Wash ZipTip 1X with 50:50 ACN:H2O
  6. Wash ZipTip 2X with 0.5% TFA solution.
  7. Run sample through ZipTip 10X SLOWLY.
  8. Wash sample 1x with 0.5% TFA in Water SLOWLY.
  9. Wash ZipTip 10X with the 20 μL aliquot of elution buffer.
  10. Dry down the sample using the SpeedVac. Once dry, resuspend the sample with 7 μL of A.
  11. Repeat as necessary with remaining samples.